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Hanamachi, Yuji*; Walker, C.*; Sasamoto, Hiroshi; Mihara, Morihiro
NIMS Bisai Kozo Kaiseki Purattofuomu Riyo Hokokusho (Internet), 2 Pages, 2023/12
A High-volume Fly ash Silica fume Cement (HFSC) has been considered as the use of concrete support of drift in deep disposal of radioactive wastes. JAEA has been carried out experiments and modeling studies to evaluate chemical stability of C-A-S-H gel synthesized which would be believed as the dominant component of the HFSC. For the modeling purpose, it is necessary to evaluate the chemical composition both of C-A-S-H gel synthesized and accompanied minerals in the experiment. In the year of 2020, 
Al and 
Si NMR measurement were performed to identify Al and Si distribution in the sample and chemical composition of C-A-S-H gel was derived. However, it was impossible to derive the C-A-S-H gel composition having the expected Al/Si molar ratio since there were several accompanied minerals produced in the experiment due to the short term of immersion. This time similar approach to derive C-A-S-H gel composition is adopted using NMR measurement for the sample of longer time (6 months).
Li, C.-Y.; Watanabe, Akira*; Uchibori, Akihiro; Okano, Yasushi
Journal of Nuclear Science and Technology, 23 Pages, 2023/00
Times Cited Count：1 Percentile：72.91(Nuclear Science & Technology)Kakiuchi, Takuhiro*; Matoba, Tomoki*; Koyama, Daisuke*; Yamamoto, Yuki*; Yoshigoe, Akitaka
Langmuir, 38(8), p.2642 - 2650, 2022/03
Times Cited Count：1 Percentile：14.86(Chemistry, Multidisciplinary)0xidation processes at the interface and the surface of Si(111) substrate with thin Hf films were studied using photoelectron spectroscopy in conjunction with supersonic oxygen molecular beams (SOMB). The oxidation starts at the outermost Hf layers and produces stoichiometric HfO
. Hf silicates (Hf-O-Si configuration) were generated in the vicinity of the HfO/Si interface in the case of the irradiation of 2.2 eV SOMB. The oxidation of the Si substrate takes place to generate SiO compounds. Si atoms were emitted from the SiO/Si interface region underneath the HfO overlayers to release the stress generated within the strained Si layers. The emitted Si atoms can pass through the HfO overlayers and react with the impinging O gas.
Walker, C.*
NIMS Bisai Kozo Kaiseki Purattofuomu Riyo Hokokusho (Internet), 2 Pages, 2021/09
High content fly ash silica fume cement (HFSC) has been considering a candidate low alkali cements for the geological disposal of radioactive waste in Japan. JAEA has been currently performing many experiments and modeling studies relevant to validation for the long-term stability of the C-A-S-H gel which is a dominant component of the HFSC. For developing the C-A-S-H model of hydration and degradation, it is necessary to determine the composition of C-A-S-H gel and accompanied minerals when it reacts with water. In the present subject, the synthesized sample of C-A-S-H gels were analyzed by using the NMR spectra of Al and Si to determine the coordination of these element in the C-A-S-H gel.
Kim, B. K.*; Tan, L.*; Sakasegawa, Hideo; Parish, C. M.*; Zhong, W.*; Tanigawa, Hiroyasu*; Kato, Yutai*
Journal of Nuclear Materials, 545, p.152634_1 - 152634_12, 2021/03
Times Cited Count：1 Percentile：16.35(Materials Science, Multidisciplinary)
7 surface using high-resolution core-level photoelectron spectroscopyKakiuchi, Takuhiro*; Matoba, Tomoki*; Koyama, Daisuke*; Yamamoto, Yuki*; Kato, Daiki*; Yoshigoe, Akitaka
Surface Science, 701, p.121691_1 - 121691_8, 2020/11
Times Cited Count：1 Percentile：6.04(Chemistry, Physical)Ultrathin hafnium films on Si(111)-77 were studied using synchrotron radiation photoelectron spectroscopies to reveal the chemical states at interface and surface. Ultrathin Hf layers grow on clean Si(111)-77 surface by lever rule. Surface and interface of Hf/Si(111) contain three components (metallic Hf layers, Hf monosilicide (HfSi) and Si-rich Hf silicide). Ultrathin Hf layers changes HfSi islands on bared Si(111)-77 surface after annealing at 1073 K. It was found that the long axes of the rectangle islands expand the direction connecting the corner holes in DAS model of clean Si(111)-77 surface.
Nakayama, Masashi
JAEA-Technology 2018-006, 43 Pages, 2018/08
JAEA-Technology-2018-006.pdf:5.32MB
JAEA-Technology-2018-006-appendix(CD-ROM).zip:29.19MB
The Horonobe URL Project has being pursued by JAEA to enhance the reliability of relevant disposal technologies through investigations of the deep geological environment within the host sedimentary formation at Horonobe, Hokkaido. The URL Project proceeds in 3 overlapping phases, "Phase I: Surface-based investigations", "Phase II: Investigations during tunnel excavation" and "Phase III: Investigations in the underground facilities", over a period of around 20 years. The OP corrosion test was prepared from 2013 FY at Niche No.3, and heating by electric heater in simulated overpack started in November, 2014. The objective of the test is acquiring data concerned with corrosion of carbon steel OP. These data will be used in order to confirm the performance of engineered barrier system. In the OP corrosion test, the diameter of simulated OP and buffer material are 100 mm and 300 mm, respectively. Concrete support using low alkaline cement was used in order to investigate the effect of cementitious materials to OP corrosion behavior. We will measure corrosion potential of carbon steel, natural potential, pH in buffer material for several years. In this report, we describe how to make simulated OP and buffer material blocks, and set sensors, and so on.
Nakayama, Masashi; Niunoya, Sumio*; Miura, Norihiko*; Takeda, Nobufumi*
JAEA-Research 2017-016, 62 Pages, 2018/01
JAEA-Research-2017-016.pdf:19.99MB
The Horonobe URL Project has being pursued by JAEA to enhance the reliability of relevant disposal technologies through investigations of the deep geological environment within the host sedimentary formation at Horonobe, Hokkaido. The URL Project consists of 2 major research areas, "Geoscientific Research" and "Research and Development on Geological Disposal Technologies", and proceeds in 3 overlapping phases, over a period of around 20 years. Phase III (Investigations in the underground facilities) investigation was started in 2010 FY. The in-situ experiment for performance confirmation of engineered barrier system (EBS experiment) had started 2013 at GL-350 m gallery, and heating by electric heater in simulated overpack had started in January, 2015. One of objectives of the EBS experiment is acquiring data concerned with THMC coupled behavior. These data will be used in order to confirm the performance of engineered barrier system. This report shows consideration of concrete-type plug composition. The low alkaline cement developed by JAEA, called HFSC, was used for the plug. HFSC has used in construction test at the gallery as shotcrete in Horonobe URL.
(am) in the aqueous K
- HCO
- CO
- OH - HO systemRai, D.*; Kitamura, Akira; Rosso, K.*
Radiochimica Acta, 105(8), p.637 - 647, 2017/08
Times Cited Count：2 Percentile：19.65(Chemistry, Inorganic & Nuclear)Solubility of HfO(am) was determined as a function of KHCO concentrations ranging from 0.001 mol.kg
to 0.1 mol.kg. The solubility of HfO(am) increased dramatically with the increase in KHCO concentrations, indicating that Hf(IV) makes strong complexes with carbonate. Thermodynamic equilibrium constants for the formation of Hf-carbonate complexes were determined using both the Pitzer and SIT models. The dramatic increase in Hf concentrations with the increase in KHCO concentrations can best be described by the formation of Hf(OH-)(CO) and Hf(CO)
. The log
K
values for the reactions [Hf
+ 2 CO +2 OH 
Hf(OH)(CO)] and [Hf + 5 CO Hf(CO)], based on the SIT model, were determined to be 44.53 
0.46 and 41.53 0.46, respectively.
Seno, Yasuhiro*; Nakayama, Masashi; Sugita, Yutaka; Tanai, Kenji; Fujita, Tomoo
JAEA-Data/Code 2016-011, 164 Pages, 2016/11
JAEA-Data-Code-2016-011.pdf:8.45MBJAEA-Data-Code-2016-011-appendix(CD-ROM).zip:0.1MB
The cementitious materials are used as candidate materials for the tunnel support of the deep geological repository of high-level radioactive wastes (HLW).Generally the pH of leachate from concrete mixed Ordinary Portland Cement (OPC) shows a range of 12 to 13. The barrier function of bentonite used as a buffer material and that of host rock might be damaged by the high alkaline leachate from cementitious materials. Therefore, low alkalinity that does not damage each barrier function is necessary for cementitious materials used for the tunnel support system of the HLW geological repository. JAEA has developed a low alkaline cement named as HFSC (Highly Fly-ash contained Silicafume Cement) which the pH of the cement leachate could lower approximately 11. We have confirmed the applicability of HFSC for the tunnel support materials, by using experimentally as the shotcreting materials to the part of gallery wall at 140m, 250m and 350m depth in Horonobe Underground Research Laboratory. And moreover, HFSC has been used as the cast-in-place concrete for the shaft lining concrete at the depth of 374m-380m. This Data/Code summarized the past HFSC mix proportion test results about the fresh concrete properties and hardened concrete properties, in order to offer the information as a reference for selecting the mix proportion of HFSC concrete adopted to the disposal galleries et al. in the future.
Liu, W.; Podowski, M. Z.*
Nihon Kikai Gakkai Netsu Kogaku Konfarensu 2016 Koen Rombunshu (USB Flash Drive), 2 Pages, 2016/10
Prediction of Critical Heat Flux (CHF) is important for nuclear reactor safety. However, the CHF prediction for subcooled flow boiling in complicated geometry such as fuel assembly still remains unsolved. As the first step for the CHF prediction in rod bundles, in this paper, we tried to predict the CHF in annulus, which is the most basic flow geometry simplified from a fuel bundle. We performed the CHF prediction by using liquid sublayer dryout model, combining with ANSYS CFX code to get the single phase velocity distribution inside the annulus. The results show that the CHF in annulus can be predicted in an accuracy of about 20%.
Seno, Yasuhiro*; Noguchi, Akira*; Nakayama, Masashi; Sugita, Yutaka; Suto, Shunkichi; Tanai, Kenji; Fujita, Tomoo; Sato, Haruo*
JAEA-Technology 2016-011, 20 Pages, 2016/07
JAEA-Technology-2016-011.pdf:7.56MB
Cementitious materials are expected to be used for the construction of an underground repository for the geological disposal of radioactive wastes. Ordinary Portland Cement(OPC) would conventionally be used in the fields of civil engineering and architecture, however, OPC has the potential to generate a highly alkaline plume (pH
12.5), which will likely degrade the performance of other barriers in the repository such as the bentonite buffer and/or host rock. Low alkaline cementitious materials are therefore being developed that will mitigate the generation of a highly alkaline plume. JAEA has developed a High-volume Fly ash Silica fume Cement (HFSC) as a candidate low alkaline cementitious material. The workability of the HFSC shotcrete was confirmed by conducting In-situ full scale construction tests in the Horonobe underground research laboratory. This report summarizes the results of immersion tests to assess the long-term pH behavior of hardened HFSC cement pastes made with mix designs that are expected to be able to be used in the construction of an underground repository in Japan.
Liu, W.; Podowski, M. Z.*
Nihon Kikai Gakkai Netsu Kogaku Konfarensu 2015 Koen Rombunshu (CD-ROM), 2 Pages, 2015/10
This paper gives prediction to the transient heat transfer at Departure of Nucleate Boiling (DNB) point for subcooled flow boiling. The prediction is carried out by solving the heat conduction equations in cylindrical coordinates with convective boundary condition, which changes with the change of the heat transfer mode on the heated surface. DNB is assumed to happen at the complete dryout of liquid sublayer trapped between the heated wall and an elongated vapor clot, during the passing time of the vapor clot. Important parameters including initial thickness of the liquid sublayer, vapor clot length, vapor clot velocity and void fraction etc., are calculated from the Liu - Nariai model. The initial heater surface temperature is derived from the Jens-Lottes correlation. The transient changes of liquid sublayer thickness, surface temperature at DNB are reported. No obvious temperature jumping is observed at DNB. To predict temperate excursion at Critical Heat Flux (CHF), more simulations to the transient boiling and film boiling processes are needed.
Ezato, Koichiro; Suzuki, Satoshi; Dairaku, Masayuki; Akiba, Masato
Fusion Engineering and Design, 81(1-7), p.347 - 354, 2006/02
Times Cited Count：12 Percentile：63.1(Nuclear Science & Technology)no abstracts in English
Ezato, Koichiro; Suzuki, Satoshi; Dairaku, Masayuki; Akiba, Masato
Fusion Engineering and Design, 75-79, p.313 - 318, 2005/11
Times Cited Count：10 Percentile：56.74(Nuclear Science & Technology)no abstracts in English
Hegeman, J. B. J.*; Van der Laan, J. G.*; Kawamura, Hiroshi; M
slang, A.*; Kupriyanov, I.*; Uchida, Munenori*; Hayashi, Kimio
Fusion Engineering and Design, 75-79, p.769 - 773, 2005/11
Times Cited Count：26 Percentile：84.04(Nuclear Science & Technology)no abstracts in English
Tian, R.; Nakajima, Norihiro; Yagawa, Genki
Keisan Kogaku Koenkai Rombunshu, 10(1), p.397 - 400, 2005/05
An attempt is made to treat boundary conditions in EFGM through only nodal arrangements. One of major merits of the proposed nodal arrangement scheme is its straightforwardness in implementation. The accuracy of this nodal arrangement boundary treatment and its influence on convergence are assessed by comparing with the Lagrange multiplier and penalty methods using one- and two- dimensional problems. The nodal arrangement scheme shows a same performance as the Lagrange multiplier and penalty methods in the one-dimensional tests, but it evidently outperforms the penalty method in the two-dimensional tests.
Cs(
= 1.63 m) by ABMRPinard, J.*; Duong, H. T.*; Marescaux, D.*; Stroke, H. H.*; Redi, O.*; Gustafsson, M.*; Nilsson, T.*; Matsuki, S.*; Kishimoto, Yasuaki*; Kominato, K.*; et al.
Nuclear Physics A, 753(1-2), p.3 - 12, 2005/05
Times Cited Count：4 Percentile：36.02(Physics, Nuclear)The hfs separation 
of Cs(
m) in the 6s 
S ground state was obtained in a precision measurement near zero magnetic field by means of atomic beam magnetic resonance with laser optical pumping on-line with the CERN-PSB-ISOLDE mass separator. The result, 
MHz, corrects significantly a previous published value from a high-field experiment. With our result, the precision of the nuclear magnetic moment, 
Cs)
, is now limited by the influence of extended nuclear structure on the hfs (the Bohr-Weisskopf effect).
Shibamoto, Yasuteru; Yonomoto, Taisuke; Nakamura, Hideo; Nishikizawa, Tomotoshi
Proceedings of 4th Japan-Korea Symposium on Nuclear Thermal Hydraulics and Safety (NTHAS-4), p.210 - 214, 2004/11
no abstracts in English
Department of Materials Science; Department of Fusion Engineering Research (Tokai Site)
JAERI-Review 2004-018, 97 Pages, 2004/08
JAERI-Review-2004-018.pdf:18.92MB
Extensive efforts for evaluating the irradiation performances of a reduced activation ferritic/martensitic steel (RAF/M) of F82H* and other several RAF/Ms have been made in recent several years. They are, examinations of the effects of neutron irradiation on (1) Ductile to brittle transition temperature (DBTT) up to a damage level of 20 dpa to explore lower temperature limit, (2) Enhanced He effect on DBTT shift for Ni/B doped heats (isotopic tailoring method was used for B doping), (3) Susceptibility to environmentally assisted cracking by the slow strain rate tensile tests (SSRT) in a high temperature pressurized water and (4) Flow stress-plastic strain relation obtained by measuring the profile of the specimen during tensile testing, together with the activities of (5) the development of the test methods after neutron irradiation and (6) other supporting researches. Results are summarized in the present report. They clearly indicate the good applicability of RAF/Ms to fusion machines.
